Peroxybenzoic acid
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Names | |||
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Preferred IUPAC name
Benzenecarboperoxoic acid | |||
Other names | |||
Identifiers | |||
93-59-4 | |||
3D model (Jmol) | Interactive image | ||
ChemSpider | 456283 | ||
ECHA InfoCard | 100.002.056 | ||
EC Number | 202-260-2 | ||
MeSH | C017611 | ||
PubChem | 523077 | ||
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Properties | |||
C7H6O3 | |||
Molar mass | 138.12 g/mol | ||
Melting point | 41 to 42 °C (106 to 108 °F; 314 to 315 K) [2] | ||
Acidity (pKa) | 7.8[2] | ||
Related compounds | |||
Related compounds |
m-Chloroperoxybenzoic acid; hydrogen peroxide; benzoic acid | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
verify (what is ?) | |||
Infobox references | |||
Peroxybenzoic acid is a simple peroxy acid. It may be synthesized from benzoic acid and hydrogen peroxide,[3] or by the treatment of benzoyl peroxide with sodium methoxide, followed by acidification.[4]
Like other peroxyacids, it may be used to generate epoxides, such as styrene oxide from styrene:[5]
References
- ↑ Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. pp. 749, 761. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4.
- 1 2 Elvers, B. et al. (ed.) (1991) Ullmann's Encyclopedia of Industrial Chemistry, 5th ed. Vol. A19, Wiley, p. 206
- ↑ Silbert, L. S.; Siegel, E.; Swern, D. (1973). "Peroxybenzoic Acid". Org. Synth.; Coll. Vol., 5, p. 904
- ↑ Géza Braun (1941). "Perbenzoic Acid". Org. Synth.; Coll. Vol., 1, p. 431
- ↑ Harold Hibbert and Pauline Burt (1941). "Styrene Oxide". Org. Synth.; Coll. Vol., 1, p. 494
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