Pentamminerhodium chloride
Cl2.png) | |
| Names | |
|---|---|
| Other names
Pentaamminechlororhodium dichloride, chloropentaamminerhodium dichloride, chloropentaamminerhodium chloride, chloropentamminerhodium(III) dichloride, chloropentamminerhodium(III) chloride | |
| Identifiers | |
| 13820-95-6 | |
| Properties | |
| [RhCl(NH3)5]Cl2 | |
| Appearance | yellow solid |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Pentamminerhodium chloride is the inorganic compound with the formula [RhCl(NH3)5]Cl2. This yellow solid is an intermediate is the purification of rhodium from its ores. As shown by X-ray crystallography, the salt consists of the octahedral complex [RhCl(NH3)5]2+ and two chloride counterions.[1] It forms from the reaction of rhodium trichloride and ammonia in ethanol.[2]
References
- ↑ Hambley, Trevor W.; Lay, Peter A. "Comparisons of π-bonding and hydrogen bonding in isomorphous compounds: [M(NH3)5Cl]Cl2 (M = Cr, Co, Rh, Ir, Ru, Os)" Inorganic Chemistry 1986, volume 25, pp. 4553-8.
- ↑ J. A. Osborn, K. Thomas, G. Wilkinson, "Pentaamminechlororhodium(III) Dichloride and Pentaamminehydridorhodium(III) Sulfate" Inorg. Syn. volume 13, pp. 213–215. doi:10.1002/9780470132449.ch43
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