Densified coal

Densified coal is the product of the Coldry Process coal upgrading technology that removes moisture from low-rank coals such as sub-bituminous and lignite/brown coal. The densification process raises the calorific value of low-rank coal to equal or exceed that of many export-grade black coals. Densified coal resulting from the Coldry Process is regarded as a black coal equivalent or replacement for black coal.[1]

Overview

Densified coal as an ostensibly ‘new’ product emanating from brown coal was first identified by Dr R.B. Johns and colleagues at the Organic Chemistry laboratory at Melbourne University following observations made at the Maddingley Mine near Bacchus Marsh, Victoria, Australia. The mine operator identified that hardened bitumen-like road surfaces formed naturally and spontaneously after heavy trucks churned up brown coal fines with moisture from rainfall when the trucks entered and left the mine. In the days that followed a rain event the road surfaces at the mine would harden like tarmac and no longer absorb water. Dr Johns and colleagues identified a process of low-mechanical shear had occurred where brown coal mixed with a small amount of moisture and subject to low-level mechanical shear had triggered a natural exothermic reaction process within the coal leading to the expulsion of its moisture content.[2] The process fundamentally alters the micro chemical bonds within the coal, naturally reducing moisture content to around 11 per cent; boosting calorific value over 5600 kcal/kg; and creating a new ‘densified coal’ product that is hydrophobic, no longer prone to spontaneous combustion, and readily transportable.

Characteristics of densified coal

The chemical and calorific values of densified coal derived from typical Victorian brown coal with a natural average moisture content of 60 per cent by weight compares well with typical high grade black coal exported from Tarong Queensland, and Newcastle New South Wales Australia.

Chemical composition

Name C Carbon % H Hydrogen % N Nitrogen % O Oxygen % S Sulfur %
Victorian Brown Coal (Lignite) 26.6 1.93 0.21 9.4 0.39
Densified Brown Coal (Coldry ) 59 4.24 0.46 21 0.85
QLD Black Coal (Export) 52 2.59 0.74 11 0.25
NSW Black Coal (Export) 48.9 3.29 1.19 10.1 0.81

Comparison of calorific values

Name Moisture % Volatiles % Fixed Carbon % Ash % Sulfur % Net Weight Specific Energy
Morwell Brown Coal (Lignite) 59.3% wb 20.0% wb 19.86% wb 0.9% wb 0.3% db 2006 kcal/kg ar

8.4 MJ/kg ar

Tarong Black Coal (Export coal) 15.5% adb 22.5% wb 44.1% wb 17.9% wb 0.42% wb 4800 kcal/kg adb

20.1 MJ/kg adb

Densified Brown Coal (Coldry) 12.0% adb 48.9% wb 49.1% wb 2.4% wb 0.3% wb 5874 kcal/kg adb

24.6 MJ/kg adb

Percent by weight

adb = as dry basis. ar = as received. db = dry basis. wb = wet basis.

See also

References

  1. ↑ Reactivity and Reactions of Australian brown coals. R.B. Johns and A.G. Pandolfo Dept Organic Chemistry, University of Melbourne. 1980
  2. ↑ Johns, R.B., Chaffee, A.L., and Verheyen, T.V. International Conference Coal Science, Dusseldorf 1981

External links

This article is issued from Wikipedia - version of the 5/4/2013. The text is available under the Creative Commons Attribution/Share Alike but additional terms may apply for the media files.